ChemicalBook > CAS DataBase List > LITHIUM TETRAMETHYLPIPERIDIDE
LITHIUM TETRAMETHYLPIPERIDIDE
- Product Name
- LITHIUM TETRAMETHYLPIPERIDIDE
- CAS No.
- 38227-87-1
- Chemical Name
- LITHIUM TETRAMETHYLPIPERIDIDE
- Synonyms
- LiTMP;LTMP;LithiuM 2,2,6,6-tetraMethylpiperidide;Piperidine, 2,2,6,6-tetramethyl-, lithium salt;piperidide;ithium 2,2,6,6-tetramethyL;LITHIUM TETRAMETHYLPIPERIDIDE;Lithium·2,2,6,6-tetramethylpiperidine;"2,2,6,6-tetramethylpiperidine lithium";Lithium (N,N,N,N-tetramethylpiperidide)
- CBNumber
- CB6365411
- Molecular Formula
- C9H18LiN
- Formula Weight
- 147.19
- MOL File
- 38227-87-1.mol
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Safety
- Hazard Codes
- F,C
- Risk Statements
- 63-14/15-34-62
- Safety Statements
- 16-26-36/37/39-43-45
- RIDADR
- UN 3131 8(4.3) / PGII
- WGK Germany
- 3
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H261In contact with water releases flammable gas
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P231+P232Handle under inert gas. Protect from moisture.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310Immediately call a POISON CENTER or doctor/physician.
P422Store contents under …
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 735353
- Product name
- Lithium 2,2,6,6-tetramethylpiperidide
- Purity
- 97%
- Packaging
- 10g
- Price
- $243
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 735353
- Product name
- Lithium 2,2,6,6-tetramethylpiperidide
- Purity
- 97%
- Packaging
- 25g
- Price
- $284
- Updated
- 2024/03/01
American Custom Chemicals Corporation
- Product number
- OGM0000655
- Product name
- LITHIUM 2,2,6,6-TETRAMETHYLPIPERIDIDE
- Purity
- 95.00%
- Packaging
- 25G
- Price
- $1275.81
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- OGM0000655
- Product name
- LITHIUM 2,2,6,6-TETRAMETHYLPIPERIDIDE
- Purity
- 95.00%
- Packaging
- 250G
- Price
- $2480.5
- Updated
- 2021/12/16
Aaron Chemicals
- Product number
- AR003RZO
- Product name
- Lithium 2,2,6,6-tetramethylpiperidide
- Purity
- 97%
- Packaging
- 1g
- Price
- $28
- Updated
- 2021/12/16
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LITHIUM TETRAMETHYLPIPERIDIDE Chemical Properties,Usage,Production
Uses
Lithium 2,2,6,6-tetramethylpiperidide is a strong base and can be used:
- For the synthesis of enamines from terminal epoxides through trans-α-lithiated epoxide as an intermediate.
- For ortholithiation of arenes such as 1,3-bis(trifluoromethyl)benzene, 4,4-dimethyl-2-phenyl-2-oxazoline, 1,4-bis(trifluoromethyl)benzene and 1,3-dimethoxybenzene.
- In combination with Lewis donor ligand, N,N,N′,N′-tetramethylethylenediamine (TMEDA) for deprotonative metalation of methoxy-substituted arenes.{21]
LITHIUM TETRAMETHYLPIPERIDIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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LITHIUM TETRAMETHYLPIPERIDIDE Suppliers
- Tel
- +1-833-552-7181
- sales@aladdinsci.com
- Country
- United States
- ProdList
- 57511
- Advantage
- 58
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